@Jaz: Lol sorry Jaz and thanks
@Ripper: Thanks - just practice and following by example. I made a few friends who have a back ground in the arts and/or photography, while learning how to make presets in SweetFX, ReShade, and/or ENB for Skyrim and FO, and they take some phenomenal images. They gave me a few tips and I try to follow some of their ideas but I lack their visual eye.
So I mainly just do casual stuff while playing. Over time you do pick up some skill and finding the right angles or field of view or perspective in making shots. My only real talent is visual organization - I am pretty good at say moving furniture and objects around visually in my head to come up with ways to say set up an office or living room or the like. In game this translates to being able to see an image and rotate it around in my head and somewhat get ideas on what might make a shot look good.
I use just a few core console commands - TFC 0 (unlocks camera from character but leaves game running, TFC 1 (unlocks camer and freezes game), SGTM .1 to 1 (changes game time speed with .1 being slowest and 1 being normal), and FOV (field of view). Less often will use TC (take control of NPC to move them) and TAI (disable AI).
Just one example I might have a character doing an animation (like running) and I will set the game time to .1 so they are moving in super slow motion. Use TFC 0 to unlock camera but keep game going - so will circle around with camera looking for a good position as the character is running in slow motion. Then use TFC 1 to freeze the game so I can then get a good angle and FOV with the camera.
Story shots I will get a lot more elaborate (with poses and such) but many I just do a single TFC 1 and take the shot pretty much as is. Just easier if you lock the game first and rotate the camera to a good angle.